Oxygen is the most abundant element on the Earth, and the third most abundant element in the universe (after hydrogen and helium). However, being highly reactive, it is usually tied up with other elements in molecules. Photosynthesis splits it off H2O. No photosynthesis, no liberated oxygen in the atmosphere.
There would be plenty of oxygen on Tatooine as can be seen in that pic - in the form of sand AKA silica AKA silicon dioxide. But not in the air.