Remember what the purpose of Alphys injecting determination to the monsters, to make it more stronger and can be break the barrier. But unfortunately, monsters are different than humans... and than it makes the monsters are melting. Undyne probably didn’t determined a lot because if Undyne has been very determined, she must be already be a amalgamate. And thats why the amalgamate are more undying than Undyne because the amalgamates are fully or mostly injected with determination by Alphys.