You may want to consider shaving a little before that. Take it from me, your neck will be very uncomfortable even with a small amount of perspiration; it will be even worse with a tux collar or uncomfortable even if you're not sweating.
You may want to consider shaving a few days in advance if you currently don't shave regularly. Then gently shaving the night before the wedding (as long as your hair doesn't grow so fast that you have a five o'clock shadow at noon.